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Oligo- and polyMOFs based on DMOF-1 adopt distinct isomeric structures governed by the flexibility, length, and number of repeat units of tethering groups between terephthalate units. 

Multitopic phosphine ligands combined with Rh(i) or Ir(i) nodes assemble into low-valent metal–organic frameworks (LVMOFs) with a two-dimensional (2D) topology and catalytic activity. 

Abstract The first James Webb Space Telescope (JWST) Near InfraRed Camera imaging in the field of the galaxy cluster PLCK G165.7+67.0 (z= 0.35) uncovered a Type Ia supernova (SN Ia) atz= 1.78, called “SN H0pe.” Three different images of this one SN were detected as a result of strong gravitational lensing, each one traversing a different path in spacetime, thereby inducing a relative delay in the arrival of each image. Follow-up JWST observations of all three SN images enabled photometric and rare spectroscopic measurements of the two relative time delays. Following strict blinding protocols which oversaw a live unblinding and regulated postunblinding changes, these two measured time delays were compared to the predictions of seven independently constructed cluster lens models to measure a value for the Hubble constant,H₀ =  71.8 + 9.2 − 8.1 km s⁻¹Mpc⁻¹. The range of admissibleH₀values predicted across the lens models limits further precision, reflecting the well-known degeneracies between lens model constraints and time delays. It has long been theorized that a way forward is to leverage a standard candle, but this has not been realized until now. For the first time, the lens models are evaluated by their agreement with the SN absolute magnifications, breaking degeneracies and producing our best estimate,H₀ =  ${75.7}_{-5.5}^{+8.1}$km s⁻¹Mpc⁻¹. This is the first precise measurement ofH₀from a multiply imaged SN Ia and only the second from any multiply imaged SN. 

Metal-Organic Frameworks (MOFs) are the subject of intense research focus due to their potential applications in gas storage and separation, biomedicine, energy, and catalysis. Recently, low-valent MOFs (LVMOFs) have been explored for their potential use as heterogeneous catalysts, and multitopic phosphine linkers have been shown as a useful building block for the formation of LVMOFs. However, the synthesis of LVMOFs using phosphine linkers requires conditions that are distinct from the majority of the MOF synthetic literature, including the exclusion of air and water and the use of unconventional modulators and solvents, making it somewhat more challenging to access these materials. This work serves as a general tutorial for the synthesis of LVMOFs with phosphine linkers, including information on: 1) judicious choice of metal precursor, modulator, and solvent; 2) experimental procedures, air-free techniques, and required equipment; 3) proper storage and handling of the resultant LVMOFs; and 4) useful characterization methods for these materials. The intention of this report is to lower the barrier and make more accessible this new subfield of MOF research and facilitate advancements toward novel catalytic materials. 

Strong gravitational magnification enables the detection of faint background sources and allows researchers to resolve their internal structures and even identify individual stars in distant galaxies. Highly magnified individual stars are useful in various applications, including studies of stellar populations in distant galaxies and constraining dark matter structures in the lensing plane. However, these applications have been hampered by the small number of individual stars observed, as typically one or a few stars are identified from each distant galaxy. Here, we report the discovery of more than 40 microlensed stars in a single galaxy behind Abell 370 at redshift of 0.725 (dubbed ‘the Dragon arc’) when the Universe was half of its current age, using James Webb Space Telescope observations with the time-domain technique. These events were found near the expected lensing critical curves, suggesting that these are magnified stars that appear as transients from intracluster stellar microlenses. Through multi-wavelength photometry, we constrained their stellar types and found that many of them are consistent with red giants or supergiants magnified by factors of hundreds. This finding reveals a high occurrence of microlensing events in the Dragon arc and demonstrates that time-domain observations by the James Webb Space Telescope could lead to the possibility of conducting statistical studies of high-redshift stars.