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Oligo- and polyMOFs based on DMOF-1 adopt distinct isomeric structures governed by the flexibility, length, and number of repeat units of tethering groups between terephthalate units. 

Abstract The first James Webb Space Telescope (JWST) Near InfraRed Camera imaging in the field of the galaxy cluster PLCK G165.7+67.0 (z= 0.35) uncovered a Type Ia supernova (SN Ia) atz= 1.78, called “SN H0pe.” Three different images of this one SN were detected as a result of strong gravitational lensing, each one traversing a different path in spacetime, thereby inducing a relative delay in the arrival of each image. Follow-up JWST observations of all three SN images enabled photometric and rare spectroscopic measurements of the two relative time delays. Following strict blinding protocols which oversaw a live unblinding and regulated postunblinding changes, these two measured time delays were compared to the predictions of seven independently constructed cluster lens models to measure a value for the Hubble constant,H₀ =  71.8 + 9.2 − 8.1 km s⁻¹Mpc⁻¹. The range of admissibleH₀values predicted across the lens models limits further precision, reflecting the well-known degeneracies between lens model constraints and time delays. It has long been theorized that a way forward is to leverage a standard candle, but this has not been realized until now. For the first time, the lens models are evaluated by their agreement with the SN absolute magnifications, breaking degeneracies and producing our best estimate,H₀ =  ${75.7}_{-5.5}^{+8.1}$km s⁻¹Mpc⁻¹. This is the first precise measurement ofH₀from a multiply imaged SN Ia and only the second from any multiply imaged SN. 

Strong gravitational magnification enables the detection of faint background sources and allows researchers to resolve their internal structures and even identify individual stars in distant galaxies. Highly magnified individual stars are useful in various applications, including studies of stellar populations in distant galaxies and constraining dark matter structures in the lensing plane. However, these applications have been hampered by the small number of individual stars observed, as typically one or a few stars are identified from each distant galaxy. Here, we report the discovery of more than 40 microlensed stars in a single galaxy behind Abell 370 at redshift of 0.725 (dubbed ‘the Dragon arc’) when the Universe was half of its current age, using James Webb Space Telescope observations with the time-domain technique. These events were found near the expected lensing critical curves, suggesting that these are magnified stars that appear as transients from intracluster stellar microlenses. Through multi-wavelength photometry, we constrained their stellar types and found that many of them are consistent with red giants or supergiants magnified by factors of hundreds. This finding reveals a high occurrence of microlensing events in the Dragon arc and demonstrates that time-domain observations by the James Webb Space Telescope could lead to the possibility of conducting statistical studies of high-redshift stars. 

Metal-Organic Frameworks (MOFs) are the subject of intense research focus due to their potential applications in gas storage and separation, biomedicine, energy, and catalysis. Recently, low-valent MOFs (LVMOFs) have been explored for their potential use as heterogeneous catalysts, and multitopic phosphine linkers have been shown as a useful building block for the formation of LVMOFs. However, the synthesis of LVMOFs using phosphine linkers requires conditions that are distinct from the majority of the MOF synthetic literature, including the exclusion of air and water and the use of unconventional modulators and solvents, making it somewhat more challenging to access these materials. This work serves as a general tutorial for the synthesis of LVMOFs with phosphine linkers, including information on: 1) judicious choice of metal precursor, modulator, and solvent; 2) experimental procedures, air-free techniques, and required equipment; 3) proper storage and handling of the resultant LVMOFs; and 4) useful characterization methods for these materials. The intention of this report is to lower the barrier and make more accessible this new subfield of MOF research and facilitate advancements toward novel catalytic materials. 

Abstract New JWST/NIRCam wide-field slitless spectroscopy provides redshifts for fourz> 8 galaxies located behind the lensing cluster MACS J0416.1−2403. Two of them, “Y1” and “JD,” have previously reported spectroscopic redshifts based on Atacama Large Millimeter/submillimeter Array measurements of [Oiii] 88μm and/or [Cii] 157.7μm lines. Y1 is a merging system of three components, and the existing redshiftz= 8.31 is confirmed. However, JD is atz= 8.34 instead of the previously claimedz= 9.28. JD’s close companion, “JD-N,” which was a previously discoveredz> 8 candidate, is now identified at the same redshift as JD. JD and JD-N form an interacting pair. A new candidate atz> 8, “f090d_018,” is also confirmed and is atz= 8.49. These four objects are likely part of an overdensity that signposts a large structure extending ∼165 kpc in projected distance and ∼48.7 Mpc in radial distance. They are magnified by less than 1 mag and have an intrinsicM_UVranging from −19.57 to −20.83 mag. Their spectral energy distributions show that the galaxies are all very young with ages ∼ 4–18 Myr and stellar masses of about 10^7–8M_⊙. These infant galaxies have very different star formation rates ranging from a few to over a hundred solar masses per year, but only two of them (JD and f090d_018) have blue rest-frame UV slopesβ< −2.0 indicative of a high Lyman-continuum photon escape fraction that could contribute significantly to the cosmic hydrogen-reionizing background. Interestingly, these two galaxies are the least massive and least active ones among the four. The other two systems have much flatter UV slopes largely because of their high dust extinction (A_V= 0.9–1.0 mag). Their much lower indicated escape fractions show that even very young, actively star-forming galaxies can have a negligible contribution to reionization when they quickly form dust throughout their bodies. 

Abstract The Prime Extragalactic Areas for Reionization and Lensing Science, a James Webb Space Telescope (JWST) GTO program, obtained a set of unique NIRCam observations that have enabled us to significantly improve the default photometric calibration across both NIRCam modules. The observations consisted of three epochs of 4-band (F150W, F200W, F356W, and F444W) NIRCam imaging in the Spitzer IRAC Dark Field (IDF). The three epochs were six months apart and spanned the full duration of Cycle 1. As the IDF is in the JWST continuous viewing zone, we were able to design the observations such that the two modules of NIRCam, modules A and B, were flipped by 180° and completely overlapped each other’s footprints in alternate epochs. We were therefore able to directly compare the photometry of the same objects observed with different modules and detectors, and we found significant photometric residuals up to ∼0.05 mag in some detectors and filters, for the default version of the calibration files that we used (jwst_1039.pmap). Moreover, there are multiplicative gradients present in the data obtained in the two long-wavelength bands. The problem is less severe in the data reduced using the latest pmap (jwst_1130.pmapas of 2023 September), but it is still present, and is non-negligible. We provide a recipe to correct for this systematic effect to bring the two modules onto a more consistent calibration, to a photometric precision better than ∼0.02 mag.